Nikolay Nikolayevich Semyonov (Russian: Никола́й Никола́евич Семёнов) (April
15 (April 3, Old Style), 1896 – September 25, 1986) was a Russian/Soviet
physicist and chemist. Semyonov was awarded the 1956 Nobel Prize in chemistry
for his work on the mechanism of chemical transformation.
Life
Semyonov was born in Saratov and graduated from the department of physics of
Petrograd University (1913–1917), where he was a student of Abram Fyodorovich
Ioffe. In 1918, he moved to Samara, where he was enlisted into Kolchak's White
Army during Russian Civil War.
In 1920, he returned to Petrograd and took charge of the electron phenomena
laboratory of the Petrograd Physico-Technical Institute. He also became he vice-director
of the intstitute. In 1921, he married philologist Maria Boreishe-Liverovsky
(student of Zhirmunsky). She died two years later. In 1923, Nikolay married
Maria's niece Natalia Nikolayevna Burtseva. She brought Nikolay a son (Yuri) and
a daughter (Lyudmila).
During that difficult time, Semyonov, together with Pyotr Kapitsa, discovered a
way to measure the magnetic field of an atomic nucleus (1922). Later the
experimental setup was improved by Otto Stern and Walther Gerlach and became
known as Stern-Gerlach experiment.
In 1925, Semyonov, together with Yakov Frenkel, studied kinetics of condensation
and adsorbtion of vapors. In 1927, he studied ionisation in gases and published
an important book, Chemistry of the Electron. In 1928, he, together with
Vladimir Fock, created a theory of thermal disruptive discharge of dielectrics.
He lectured at the Petrograd Polytechnical Institute and was appointed Professor
in 1928. In 1931, he organized the Institute of Chemical Physics of the U.S.S.R.
Academy of Sciences (which has moved to Chernogolovka in 1943) and became its
first director. In 1932, he became a full member of the Soviet Academy of
Sciences.
Significant works
Semyonov's outstanding work on the mechanism of chemical transformation includes
an exhaustive analysis of the application of the chain theory to varied
reactions (1934–1954) and, more significantly, to combustion processes. He
proposed a theory of degenerate branching, which led to a better understanding
of the phenomena associated with the induction periods of oxidation processes.
Semyonov wrote two important books outlining his work. Chemical Kinetics and
Chain Reactions was published in 1934 with an English edition in 1935. It was
the first book in the U.S.S.R. to develop a detailed theory of unbranched and
branched chain reactions in chemistry. Some Problems of Chemical Kinetics and
Reactivity, first published in 1954, was revised in 1958; there are also English,
American, German, and Chinese editions.
In 1956, he was awarded the Nobel Prize in Chemistry (together with Sir Cyril
Norman Hinshelwood) for this work. Semyonov also became a Hero of Socialist
Labor twice, received two Stalin Prizes, five Orders of Lenin, and many other
awards.
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