Friedrich Wilhelm Ostwald (commonly just Wilhelm Ostwald) (September 2, 1853
- April 4, 1932) was a German chemist. He received the Nobel Prize in Chemistry
in 1909 for his work on catalysis, chemical equilibria and reaction velocities.
Biography
He was born in Riga (at that time Russia, today Latvia), as the son of master-cooper
Gottfried Wilhelm Ostwald and Elisabeth Leuckel. He was ethnically a Baltic
German. He graduated from the University of Tartu in 1875, he received his Phd
there in 1878 under the guidance of Carl Schmidt and taught at Tartu from 1875
to 1881 and Riga Polytechnicum from 1881 to 1887. In 1887, he moved to Leipzig
where he worked for the rest of his life. Arthur Noyes was one of his famous
students, as was Willis Rodney Whitney.
Overview
He is usually credited with inventing the Ostwald process (patent 1902), used in
the manufacture of nitric acid, although the basic chemistry had been patented
some 64 years earlier by Kuhlmann, when it was probably of only academic
interest due to the lack of a significant source of ammonia. That may have still
been the state of affairs in 1902, although things were due to change
dramatically in the second half of the decade as a result of Haber and Bosch's
work on their nitrogen fixing process (completed by 1911 or 1913). The date 1908
(six years after the patent) is often given for the invention of the Ostwald
process, and it may be that these developments motivated him to do additional
work to commercialize the process in that time-frame. Alternatively, six years
might simply have been the bureaucratic interval between filing the patent and
the time it was granted.
The combination of these two breakthroughs soon led to more economical and
larger-scale production of fertilizers and explosives which Germany was to find
itself in desperate need of during World War I. Ostwald also did significant
work on dilution theory leading to his discovery of the law of dilution which is
named after him.
The word mole, according to Gorin, was introduced into chemistry around 1900 by
Ostwald. Ostwald defined one mole as the molecular weight of a substance in mass
grams. The concept was linked to the ideal gas, according to Ostwald. Ironically,
Ostwald's development of the mole concept was directly related to his
philosophical opposition to the atomic theory, against which he (along with
Ernst Mach) was one of the last holdouts. He explained in a conversation with
Arnold Sommerfeld that he was converted by Einstein's explanation of Brownian
Motion[citation needed].
Ostwald was a member of the International Committee on Atomic Weights. Due to
World War I this membership ended in 1917 and was not resumed after the war. The
1917 Annual report of the committee ended with the unusual note: "Because of the
European war the Committee has had much difficulty in the way of correspondence.
The German member, Professor Ostwald, has not been heard from in connection with
this report. Possibly the censorship of letters, either in Germany or en route,
has led to a miscarriage".
In addition to his work in chemistry, Wilhelm Ostwald was very productive in an
extremely broad range of fields. His published work, which includes numerous
philosophical writings, contains about forty thousand pages.
Ostwald died in a hospital in Leipzig on April 4, 1932.
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